Background Image

Dan Goia

In this Section
Goia
CAMP Distinguished Professor
Chemistry & Biomolecular Science
317 CAMP
Clarkson University
PO Box 5814
Potsdam, NY 13699-5814
Phone: 315-268-4411
E-mail: goiadanv@clarkson.edu
Web site: http://www.clarkson.edu/goia

Educational Background
Ph.D. Chemistry, Clarkson University, 1998
M.S. Chemistry, University of Cluj, Romania, 1980
B.S. Chemistry, University of Cluj, Romania, 1979

Research Interests
Our research is focused mainly on the synthesis, characterization, and modification of highly dispersed uniform micrometer, submicrometer, and nanometer size metallic particles with well controlled size, morphology, internal structure, composition, and surface properties. While our efforts are primarily focused on the development of chemical precipitation processes capable of yielding high performance materials for existing and emerging applications, we also conduct the basic research needed to understand the mechanisms responsible for the formation of uniform metallic particles in solutions. Regarding the first aspect, we have successfully developed many novel precipitation methods for economically generating highly dispersed metallic particles of Cu, Ni, Co, Bi, Ag, Au, Pd, Pt, and their alloys for applications in electronics, energy conversion and storage (PEM and SO fuel cells), medicine and biology, emissions control, sensors, and metallurgy. At the same time, our experimental and modeling work on spherical gold and silver particles has contributed to the understanding of the formation mechanism of large uniform colloids in homogeneous solutions by aggregation of nanosize precursors and has resulted in a model that is now widely accepted by the scientific community and is frequently cited in the literature. 


Another rather unique expertise of our group consists of the ability to convert ultrafine uniform metallic particles into metallic platelets/flakes by physical processes. Although under-researched, this interdisciplinary area bordering colloid and surface science, physics, and metallurgy has a significant impact on many applications in defense (obscurant smokes) and electronics. Finally, our knowledge and experience in the preparation and modification of fine metallic particles represents a solid foundation that allows us to do independent research as well as to collaborate effectively with various research groups and companies involved in the development of metallic dispersions and inks for applications in electronics, pigments, catalysis, photonics, coatings, and sensors.


Current Research Project/Grants

“Development and Modification of Compounds for Utilization in Homogeneous and Heterogeneous Chemical Catalysis”; sponsored by Umicore, Inc., Germany/Belgium

“Synthesis and Modification of Precious Metal Particles with Controlled Size, Shape and Surface Functionality for Electronic Applications”, sponsored by Johnson Matthey, Inc.

“NY-BEST Market Driven Research Program with GE Global (Task 4)”; sponsored by General Electric/NYSERDA

“Improved Metal Coated Polymer Particles”; sponsored by Conpart, AS, Norway


Peer Reviewed Journal Articles (2010 – Present)

“Precipitation of spherical and ‘fiber-like’ silver particles”, L. Lu, DV Goia, Journal of Colloid and Interface Science, 407 (2013), 122-127,  DOI: 10.1016/j.jcis.2013.06.023.

“Preparation of dispersed spherical platinum particles with controlled size and internal structure”, BP Farrell, I. Sevonkaev, DV Goia, Platinum Metals Review, 57, 3, (2013), 161-168, DOI: 10.1595/147106713X667605.

“Core-shell gold/silver nanoparticles: synthesis and optical properties”, L. Lu, G. Burkey, I. Halaciuga, DV Goia, Journal of Colloid and Interface Science, 392 (2013), 90-95, DOI: 10.1016/j.jcis.2012.09.057.

“Growth of highly crystalline nickel particles by diffusional capture of atoms”, I. Sevonkaev, V. Privman, DV Goia, The Journal of Chemical Physics, 183, 1, (2013), 014703 (6 pages), DOI: 10.1063/1.4772743.

“Synthesis of dispersed metal particles for applications in photovoltaic, catalysis and electronics”, I. Sevonkaev, V. Privman, D. V. Goia;   Journal of Solid State Electrochemistry, 17, (2012), 279-297, DOI: 10.1007/s.10008-012-1954-6.

”Deposition of continuous nickel shells on polymer microspheres”, I. Halaciuga, J.I. Njagi, K. Redford, D.V. Goia; Journal of Colloid and Interface Science, 383, 1, (2012), 215-221, DOI: 10.1016/j.jcis.2012.05.055.

”Precipitation of silver/palladium alloy platelets from homogeneous solutions”, L. Lu, B. P. Farrell, D.V. Goia, Journal of Colloid and Interface Science, 376, 1, (2012), 62-66,  DOI: 10.1016/j.jcis.2012.03.016.

”Electrochemical features of ball-milled lithium manganate spinel for rapid charge cathodes of lithium ion batteries”, D.J. Crain, J.P. Zheng, C.M. Sulyma, C. Goia, D.V. Goia, D. Roy, Journal of Solid State Electrochemistry, 16, 8, (2012), 2605-2615, DOI: 10.1007/s10008-012-1677-8.

”Deposition of continuous platinum shells on gold nanoparticles by chemical precipitation”, R. Roy, J. Njagi, B. Farrell, I. Halaciuga and D.V. Goia, Journal of Colloid and Interface Science,369, (2012), 91-95, DOI:10.1016/j.jcis.2011.11.068.

“Preparation of counterion stabilized concentrated silver sols”, S. LaPlante, I. Halaciuga, D.V. Goia, Journal of Colloid and Interface Science”,359, 1, (2011), 121-125, DOI: 10.1016/j.jcis.2011.03.080.

“Precipitation of dispersed silver particles using acetone as reducing agent”, I. Halaciuga, S. LaPlante, D.V. Goia, Journal of Colloid and Interface Science, 354, (2011), 620-623, DOI: 10.1016/j.jcis.2010.11.014.

“Au Pt core-shell Nanocatalysts with bulk Pt activity”, K. Hartl, K. J.J. Mayrhofer, M. Lopez, D. Goia, M. Arenz, Electrochemistry Communications 12 (2010) 1487-1489, DOI:  10.1016/j.elecom.2010.08.013.


Book Chapters
“Biomedical Applications of Gold Nanoparticles”, Tapan K. Sau and Dan V. Goia, In: Fine Particles in Medicine and Pharmacy, Ed. Egon Matijević, Springer, New York, 2011, DOI 10.1007/978-1-4614-0379-1
 

Presentations (2010 - Present)
“Preparation and Formation Mechanisms of Metallic Particles with Controlled Size, Shape, Structure and Surface Functionality, L. Lu, DV Goia, Woonsocket, RI, February 2013.

“Epitaxial Deposition of Thin Platinum Shells on Gold Nanocrystals”, B. Farrell, M. Lopez, J. Njagi, D.V. Goia, ACS National Meeting & Exposition, “Half a Century of Fine Particles Science: A Symposium in Honor of Egon Matijevic at 90”, Philadelphia, PA, August 22, 2012.

“Synthesis of Au/Pd/Pt Core-Shell-Shell Catalysts for PEM Fuel Cells,” Dr. Igor Sevonkaev, Dr. John I. Njagi, Lu Lu , Dr. Dan  V. Goia,  Dr. Marco Lopez, Gordon Research Conference, August, 2012.

“Core-Shell Pt Based Electrocatalysts”, D.V. Goia, CAMP Annual Technical Meeting 2012, CAMP, Clarkson University, Albany, NY, USA, May 17, 2012.

“Metal Coated Polymer Particles for Electronic Packaging”, I. Halaciuga, K. Redford, D. V.  Goia, IMAPS 2010:,International Symposium on Microelectronics, Research Triangle Park, NC, November 2010; Best Paper in Session Award.

“Inkjet Printable Dispersions of Gold and Silver Nanoparticles”, K. Balantrapu, L. Lu, I. Halaciuga, D.V. Goia, IMAPS 2010: International Symposium on Microelectronics, Research Triangle Park NC, November 2010.

“Synthesis and applications of highly dispersed uniform metallic nanoparticles”, K. Balantrapu, I. Halaciuga, D.V. Goia, PowderMet 2010, International Conference on Powder Metallurgy and Particulate Materials, Special Interest Program, Fort Lauderdale, FL, June 2010.


Patents (2010 – Present)
‘Aqueous-based method for producing ultra-fine metal powders’, Goia, DV, Andreescu, D., Eastman, C., US Patent # US 8,470,066, June 25, 2013.

‘Silver platelets comprising palladium’, Goia, DV, Farrell, BP, US Patent # US 8,084,140, March 1, 2013.

‘Core/shell-type catalyst particles and methods for their preparation’, Goia, D.V., Lopez, M., Lennartz, M., Becker, C., Chevalliot, S., US Patent # 8,288,308 B2, October 16, 2012.

'Manufacture of base metal nanoparticles using a seed particle method', Goia, D.V., Lopez, M., Sevonkaev, I., International Publication # WO 2012/123442 A1, September 20, 2012.

'Core/shell-type catalyst particles comprising metal or ceramic core materials and methods for their preparation', Goia, D.V., Lopez, M., Lennartz, M., Becker, C., Chevalliot, S., Chinese Patent # ZL200780037674.7, August 29, 2012.

'Core/shell-type catalyst particles comprising metal or ceramic core materials and methods for their preparation', Goia, D.V., Lopez, M., Lennartz, M., Becker, C., Chevalliot, S., US Patent # US 8,227,372 B2, July, 24, 2012.

'Method for producing dispersed, crystalline, stable to oxidation copper particles', Goia, D.V., Halaciuga, I., LaPlante, S.C., Glicksman, H.D., US Patent # US 8,216,340 B2, July 10, 2012.

'Process for the surface modification of a polymer particle', Goia, D.V., Redford, K., Halaciuga, I., Braein Nilsen, C., International Publication # WO 2012/056244 A1, May 3, 2012.

'Silver platelets comprising palladium', Goia, D.V., Farrell, B.P., US Patent # US 8,084,140, December 27, 2011.

'Noble metal nanoparticles, a process for preparing these and their use', Starz, K-A., Goia, D.V., Koehler, J., Banisch, V., US Patent # US 8,071,259,B2, December 6, 2011.

'Use of polyamines for the surface preparation of particles', Goia, D.V., Halaciuga, I., Redford, K., International Patent Application (UK) # PCT/GB2011/052101, October 28, 2011. 

'Process for manufacture of silver-based particles and electrical contact materials', Goia, D.V., Fritzsche, S., Kempf, B., Braumann, P., Thierry, C.S., Valdevelde, U.S. Patent # US 7,842,274 B2, November 30, 2010.

'Method for producing dispersed, crystalline, stable to oxidation copper particles', Goia, D.V., Halaciuga, I., LaPlante, S.C., Glicksman, H.D., International Publication #WO 2010/102010 A1, September 10, 2010.

'Method for manufacture of noble metal alloy catalysts and catalysts prepared therewith', Goia, D.V., Lopez, M., Sau, T. K., Jitianu, M., US Patent No.: US 7,713,910 B2, May 11, 2010.


Facilities
Jeol JEM 2010 High Resolution Scanning Transmission Electron Microscope
Jeol JSM 7400F High Resolution Field Emission Scanning Electron Microscope
Bruker D8 X-Ray Diffractometer
Malvern Mastersizer 2000s Laser Diffraction Particle Size Analyzer
Brookhaven ZetaPlus Particle Size and Zeta Potential Analyzer
Perkin Elmer Pyris 1 Thermogravimetric Analyzer
TA Instruments TMA Q400 Thermomechanical Analyzer
Quantachrome NOVA 1200e BET Surface Area and Pore Analyzer
Perkin Elmer Lambda 35 UV-Vis Spectrophotometer
Dimatix Inkjet Printer DMP-2831
Ambios Technology XP-2 Surface Profilometer
  

Research Associates
Corina Goia
Igor Sevonkaev

John Njagi
Angshuman Pal
Ajeet Kumar

Graduate Students
Christopher Netzband
Dinusha Karunaratne

Recent Graduates
Sylas LaPlante, PhD, May 2012, Research Chemist, Ames Goldsmith Corporation, Glens Falls, NY
Lu Lu, PhD, May 2013, Research Scientist, Technic, Inc., Woonsocket, RI